James Milner will don the armband while Divock Origi will replace Sadio Mane when Liverpool take on Chelsea in the FA Cup on Tuesday.
Divock Origi is the only change for Liverpool from their most recent Premier League outing as they get set to take on West Ham United at the London Stadium.
Sadio Mane has been ruled out for Liverpool while Divock Origi will start again when the Reds take on West Ham United on Wednesday.
Takumi Minamino is set to make his Liverpool debut, while Divock Origi and Rhian Brewster should return when the Reds take on Everton in the FA Cup third round.
Liverpool will be hoping to book their place in the FA Cup fourth round when they welcome local rivals Everton to Anfield on Sunday.
Virgil van Dijk is set to turn out for Liverpool for the 100th time while Divock Origi should replace Sadio Mane when the Reds face Wolves on Sunday.
A place in the Club World Cup final will be on the line when Liverpool take on Monterrey at the Khalifa International Stadium on Wednesday.
Liverpool will hope to continue their fine unbeaten run in the Premier League when they take on Bournemouth at Dean Court on Saturday.
Divock Origi and Sadio Mane were in sensational touch as Liverpool ran out 5-2 winners over Everton in the first Merseyside derby of the season on Wednesday.
Roberto Firmino and Sadio Mane are among those who have been benched, while Divock Origi starts for Liverpool as they welcome Genk to Anfield.