Cameroon and Australia will look to move on from defeats in their first matches when they face off at Stadion Krestovsky on Thursday.
Russia host Portugal in their second Group A Confederations Cup match at the Otkrytiye Arena in Moscow on Wednesday.
Mexico and New Zealand are set to meet in Sochi's Fisht Stadium on Wednesday, and both teams will be equally under pressure to win this game
The young German side triumphed in a thrilling encounter against Australia as they were brilliantly lead by Julian Draxler and picked three crucial points.
Arturo Vidal scored the all important goal in the last 10 minutes of the game to power Chile to a win over Colombia in Group B of the FIFA Confederations Cup 2017.
The second match in Group A ended all squad as Mexico held Portugal to a late 2-2 draw at the Kazan Arena on Sunday.
Australia and Germany will go head-to-head in Group B of the FIFA Confederations Cup as either side will be looking to open their account with a win.
The champions of South America meet the champions of Africa, as Chile take on Cameroon in a Group B encounter of the Confederations Cup
Euro 2016 champions Portugal open their Confederations Cup campaign against 2015 CONCAF Cup winners Mexico.
The 2017 FIFA Confederations Cup will kick-off with hosts Russia welcoming New Zealand to the Krestovsky Stadium in Saint Petersburg